CN103265220B - Powdery mica foaming agent - Google Patents

Powdery mica foaming agent Download PDF

Info

Publication number
CN103265220B
CN103265220B CN201310223199.XA CN201310223199A CN103265220B CN 103265220 B CN103265220 B CN 103265220B CN 201310223199 A CN201310223199 A CN 201310223199A CN 103265220 B CN103265220 B CN 103265220B
Authority
CN
China
Prior art keywords
attapulgite clay
foaming agent
powdery mica
mica
powdery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201310223199.XA
Other languages
Chinese (zh)
Other versions
CN103265220A (en
Inventor
许庆华
蒋文兰
许盛英
袁长兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zheng Zonghua
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201310223199.XA priority Critical patent/CN103265220B/en
Publication of CN103265220A publication Critical patent/CN103265220A/en
Application granted granted Critical
Publication of CN103265220B publication Critical patent/CN103265220B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Detergent Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a powdery mica foaming agent. The foaming agent comprises sericite, high-viscosity attapulgite clay powder, active attapulgite clay, sodium dodecyl sulfate, sodium percarbonate, sodium polyacrylate, sodium pyrophosphate and sodium poly[(naphthaleneformaldehyde)sulfonate]. The finished product of the powdery mica foaming agent is produced by stirring ingredients of the powdery mica foaming agent, milling the ingredients into powder and packaging the powder. The powdery mica foaming agent has the advantages that the powdery mica foaming agent has strong foaming capacity, high foam expansion and high foam yield in unit volume, has good foam outer membrane tenacity and is not easy to break, has good foam stability, can not be defoamed for a long time, is exquisite in foam, is uniform in sizes of holes generated in media and has low bleeding quantity and good compatibility of used media. The products produced by using the powdery mica foaming agent not only can effectively control noise pollution but also have the functions of preserving heat and purifying air. The powdery mica foaming agent is suitable for producing lightweight boards, lightweight walls and noise reducing products.

Description

Powdery mica whipping agent
Technical field
The present invention relates to whipping agent, be specifically related to a kind of powdery mica whipping agent.
Background technology
City noise is having a strong impact on city resident's orthobiosis and health of human body, city noise mainly refers to traffic noise, factory noise, construction noise pollution and noise of social activities, the range of influence of its noise and influence degree are day by day serious, on the impact of civic living environment greatly, become one of noticeable city environmental pollution problem.
Control noise and conventionally take the measures such as damping, sound insulation, sound absorption, sourdine, personal protection and architectural composition, weaken as far as possible or reduce the vibration of sound source, acoustic energy absorption in propagating is fallen, place obstacles and make that sound is all or part of to be reflected away, weaken the effect of noise, to reach the object of controlling noise.
Conventionally adopt quieter material to produce the products such as some acoustical panels, sound insulation Wall, sound-absorbing net and sound damper and control sound pollution, also having some materials is after processing by foaming, to improve the performance of the said products.
The kind of whipping agent is more, made larger contribution, but the said products can only be for controlling sound pollution, the function not purifying air for controlling sound pollution.
Summary of the invention
The object of the invention is to overcome weak point in prior art, a kind of powdery mica whipping agent is provided.
Powdery mica whipping agent is comprised of sericite, high sticky attapulgite clay powder, activated attapulgite, sodium lauryl sulphate, SPC-D, sodium polyacrylate, trisodium phosphate and poly-naphthaldehyde sulfonate sodium.
The production method of powdery mica whipping agent: by stirring in powdery mica whipping agent batching input stirrer, input after stirring in grinding machine and carry out abrasive dust, be packaged as the finished product of powdery mica whipping agent.
Mica has the characteristics such as good elasticity, toughness, insulativity, high temperature resistant, acid and alkali-resistance, corrosion-resistant, strong adhesion and satin luster, sericite has high resistance, excellent insulating material and fire-retardant filler, sericite can significantly change the series of physical modulus of material, form or change the visco-elasticity of material, this class material is absorbing vibrational energy, weakening shock wave and sound wave expeditiously, is used to prepare noise elimination, sound insulation, damping coating, and the present invention selects sericite.
Attapulgite has another name called polygorskite or Palygorskite, be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, attapulgite has unique layer chain-like structure feature, in its structure, there is crystal lattice, therefore contain Na+, Ca2+, Fe3+, the Al3+ of non-quantitative in crystal, crystal is needle-like, fibrous or fiber collection shape.Attapulgite has unique dispersion, high temperature resistant, the anti-good colloidal property such as saline and alkaline and higher adsorptive power, and has certain plasticity-and cohesive force.
High sticky attapulgite clay is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, attapulgite clay soil property is fine and smooth, there is oily soapy, light weight, property are crisp, fracture is conchoidal or irregular shape, and water-absorbent is strong, tool viscosity and plasticity-when wet, more than its viscosity can reach 3000mPas, be conducive to the bonding between raw material.
High sticky attapulgite clay powder refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250ml through high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value>=2200 into mPasattapulgite clay powder.
The pH value of attapulgite clay raw ore is 8~9, need in the present invention to carry out acidification, attapulgite clay after acidified processing is activated attapulgite, the various performances of activated attapulgite all will be greatly improved, particularly strengthened the adsorption cleaning ability of Attapulgite, it is 5.5~7.5 that activated attapulgite pH value is controlled, water content≤2%.
Sodium lauryl sulphate is white or faint yellow powdery, water-soluble, insensitive to alkali and hard water, has decontamination, emulsification and excellent foaming power, is a kind of nontoxic anion surfactant; When powdery mica whipping agent and water mix, a large amount of bubble of the common generation of sodium lauryl sulphate and SPC-D.
SPC-D is a kind of inorganic salt, and the granulated powders that is white in color can be decomposed rapidly after SPC-D contacts with water, discharges a large amount of oxygen.
Sodium polyacrylate is a kind of new functional macromolecule material, for white or buff powder, be dissolved in cold water, stable to temperature variation, be a kind of tensio-active agent with multiple property, be conducive in the present invention improve the effect of the thickening, foaming of powdery mica whipping agent, stable, emulsification, dispersion, bonding, film forming and water conservation.
Trisodium phosphate is a kind of water white transparency crystallization or white crystalline powder, soluble in water, in the present invention as dispersion agent and emulsifying agent.
Poly-naphthaldehyde sulfonate sodium is brown or dark-brown powder, and soluble in water, acidproof, alkaline-resisting, resistance to hard water, has good diffustivity; When powdery mica whipping agent and water mix, generate a large amount of bubbles, it is more even that trisodium phosphate and poly-naphthaldehyde sulfonate sodium are conducive to the bubble distribution of generation.
The present invention is achieved by following technical proposals:
1, powdery mica whipping agent batching is comprised of following component by weight percentage: sericite 15~45%, high sticky attapulgite clay powder 5~20%, activated attapulgite 5~25%, sodium lauryl sulphate 1~35%, SPC-D 1~25%, sodium polyacrylate 0.01~5%, trisodium phosphate 0.01~5% and poly-naphthaldehyde sulfonate sodium 0.01~5%.
The production method of described powdery mica whipping agent: by stirring in powdery mica whipping agent batching input stirrer, input in grinding machine and carry out abrasive dust after stirring, particle fineness≤0.074 millimeter, is packaged as the finished product of powdery mica whipping agent.
The sticky attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, it is characterized in that, and from the attapulgite clay of mining area exploitation, need to be through the weathering of 30~120 days; Modification processing method is: calculate by weight percentage, get the attapulgite clay 94~98% after weathering, evenly add 2~6% sodium carbonate, jointly input in fermentation vat, add clear water to soak ageing, soak time is 72~120 hours; Get the attapulgite clay after immersion, in input stirrer, stir, and by the attapulgite clay after stirring, through extrusion machine, be extruded into thin slice, its gauge control is at 0.5~2 millimeter, by attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after airing, its water content≤15%; Batching is calculated by weight percentage: the attapulgite clay 94~98% after airing, High hydrophilous resin 0.5~5% and Mierocrystalline cellulose 0.5~3%, above-mentioned batching is stirred, and after stirring, input and in grinding machine, carry out abrasive dust, particle fineness≤0.074 millimeter.
Above-mentioned production technique is to adopt " the improving the complete processing of viscosity of attapulgite clay " of being applied on June 20th, 2005 by the inventor, and Chinese patent Granted publication number is: CN 1317067C, Granted publication day: on May 23rd, 2007.
The production method of described activated attapulgite is: the 1. preparation of dilute sulphuric acid, is comprised of following component by weight percentage: the sulfuric acid 3~5% of concentration 98 ﹪, water 95~97%; 2. the batching of acidification, comprises following component by weight percentage: attapulgite clay raw ore 55~65%, and dilute sulphuric acid 35~45%, slowly adds dilute sulphuric acid and in attapulgite clay raw ore, carries out acidification; 3. extruding: by Concavo-convex excellent stone clay after the acidify, push as flap thickness≤3 millimeter of flap by extrusion machine; 4. roasting: the flap of attapulgite clay is transported in stoving oven and carries out roasting, and roasting time is 1.5~3 hours, and maturing temperature is controlled at 320~450 ℃, and the attapulgite clay flap after roasting is activated attapulgite.
This production method is the production method that adopts the activated attapulgite in " embossed rod medicinal health-care bathing-mud powder " of application on March 7th, 2006 by the inventor, the China Patent Publication No. of embossed rod medicinal health-care bathing-mud powder is: CN1850026, open day: on October 25th, 2006.
Described water content is weight percentage.
Powdery mica whipping agent is added in medium; after water mixing and stirring; can discharge a large amount of gas; in medium, produce a large amount of even and stable foams; be used for pouring into a mould multiple foam materials product, there will not be layering in casting process, the product stripping time is shorter; gas contains a certain amount of oxygen, is conducive to protect the air ambient of working-yard.
The applicable medium of powdery mica whipping agent has the materials such as various cement, flyash and nonmetalliferous ore composition.
During simple use sodium lauryl sulphate, foam generated is very fast, but what break and disappear is also fast, cause the less stable of foam, in the present invention, after sericite and other batching and sodium lauryl sulphate compatibility, formed a kind of compound foaming agent, have that foaming power is strong, foam expansion is high, unit volume bubble production volume is large, foam adventitia good toughness is difficult for brokenly, froth stability is good, can be for a long time not froth breaking, the advantage such as foam hole size fine and smooth, that generate in medium is even, bleeding quantity is low and the consistency of working medium is good.
The product that uses powdery mica whipping agent to produce, not only can effectively control sound pollution, the function that is incubated in addition and purifies air; These products are for facilities such as motorway, viaduct, urban light rail, subway, factory, warehouse, public places.
Powdery mica whipping agent is applicable to produce light weight board, Light Wall and sound-deadening and noise-reducing product.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, powdery mica whipping agent batching is comprised of following component by weight percentage: sericite 28%, high sticky attapulgite clay powder 10%, activated attapulgite 22%, sodium lauryl sulphate 26%, SPC-D 12.3%, sodium polyacrylate 0.8%, trisodium phosphate 0.6% and poly-naphthaldehyde sulfonate sodium 0.3%.
The production method of described powdery mica whipping agent: by stirring in powdery mica whipping agent batching input stirrer, input in grinding machine and carry out abrasive dust after stirring, particle fineness≤0.044 millimeter, is packaged as the finished product of powdery mica whipping agent.

Claims (1)

1. a powdery mica whipping agent, it is characterized in that, powdery mica whipping agent batching is comprised of following component by weight percentage: sericite 15~45%, high sticky attapulgite clay powder 5~20%, activated attapulgite 5~25%, sodium lauryl sulphate 1~35%, SPC-D 1~25%, sodium polyacrylate 0.01~5%, trisodium phosphate 0.01~5% and poly-naphthaldehyde sulfonate sodium 0.01~5%;
The production method of described powdery mica whipping agent: by stirring in powdery mica whipping agent batching input stirrer, input in grinding machine and carry out abrasive dust after stirring, particle fineness≤0.074 millimeter, is packaged as the finished product of powdery mica whipping agent;
The sticky attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, it is characterized in that, and from the attapulgite clay of mining area exploitation, need to be through the weathering of 30~120 days; Modification processing method is: calculate by weight percentage, get the attapulgite clay 94~98% after weathering, evenly add 2~6% sodium carbonate, jointly input in fermentation vat, add clear water to soak ageing, soak time is 72~120 hours; Get the attapulgite clay after immersion, in input stirrer, stir, and by the attapulgite clay after stirring, through extrusion machine, be extruded into thin slice, its gauge control is at 0.5~2 millimeter, by attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after airing, its water content≤15%; Batching is calculated by weight percentage: the attapulgite clay 94~98% after airing, High hydrophilous resin 0.5~5% and Mierocrystalline cellulose 0.5~3%, above-mentioned batching is stirred, and after stirring, input and in grinding machine, carry out abrasive dust, particle fineness≤0.074 millimeter;
The sticky attapulgite clay powder of described height refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250mL through high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value>=2200 into mPasattapulgite clay powder.
CN201310223199.XA 2013-06-07 2013-06-07 Powdery mica foaming agent Active CN103265220B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310223199.XA CN103265220B (en) 2013-06-07 2013-06-07 Powdery mica foaming agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310223199.XA CN103265220B (en) 2013-06-07 2013-06-07 Powdery mica foaming agent

Publications (2)

Publication Number Publication Date
CN103265220A CN103265220A (en) 2013-08-28
CN103265220B true CN103265220B (en) 2014-11-05

Family

ID=49008899

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310223199.XA Active CN103265220B (en) 2013-06-07 2013-06-07 Powdery mica foaming agent

Country Status (1)

Country Link
CN (1) CN103265220B (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040028956A1 (en) * 2002-08-07 2004-02-12 Arpad Savoly Dispersant and foaming agent combination
CN101037312A (en) * 2006-03-16 2007-09-19 上海华联建筑外加剂厂有限公司 Middle-effective pumping aid

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2933994B2 (en) * 1990-07-10 1999-08-16 花王株式会社 Admixture for cement

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040028956A1 (en) * 2002-08-07 2004-02-12 Arpad Savoly Dispersant and foaming agent combination
CN101037312A (en) * 2006-03-16 2007-09-19 上海华联建筑外加剂厂有限公司 Middle-effective pumping aid

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP平4-74748A 1992.03.10 *

Also Published As

Publication number Publication date
CN103265220A (en) 2013-08-28

Similar Documents

Publication Publication Date Title
CN103265318B (en) Powdery talcum foaming agent
CN103265214B (en) Powdery bentonite foamer
CN103253966B (en) Powdery boric sludge foaming agent
CN103253887B (en) Powder coal ash foaming agent
CN103253971B (en) Powdery calcium carbonate foaming agent
CN103265218B (en) Powdery water-quenched slag foaming agent
CN103265308B (en) Powdery red mud foamer
CN103265317B (en) Powdery magnesium oxide foaming agent
CN103253958B (en) Powdery carbide slag foaming agent
CN103265221B (en) Powdery basalt foaming agent
CN103265312B (en) Powdery gypsum foaming agent
CN103253888B (en) Powder pumice foaming agent
CN103265307B (en) Powdery kieselguhr foamer
CN103274623B (en) Powdery zeolite foaming agent
CN103253955B (en) Powder bauxite foaming agent
CN103274629B (en) Powdery gangue foaming agent
CN103265219B (en) Powdery quicklime foaming agent
CN103265311B (en) Powdery cement foaming agent
CN103265309B (en) Powdery rectorite foamer
CN103253963B (en) Powdery volcanic ash foaming agent
CN103265216B (en) Powdery maifan stone foaming agent
CN103265222B (en) Powdery serpentine foaming agent
CN103265323B (en) Powdery shale foaming agent
CN103274631B (en) Powdery sludge foaming agent
CN103265215B (en) Powdery phosphogypsum foaming agent

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20170315

Address after: 510640 unit 371-1, public education building, 2414-2416, No. five, Tianhe District, Guangzhou, Guangdong

Patentee after: Guangdong Gaohang Intellectual Property Operation Co., Ltd.

Address before: 211700 Huaian, Xuyi province Timor King international residential area, building 2, unit 202 room 18

Patentee before: Xu Shengying

TR01 Transfer of patent right
CB03 Change of inventor or designer information

Inventor after: Ou Yangyun

Inventor before: Xu Qinghua

Inventor before: Jiang Wenlan

Inventor before: Xu Shengying

Inventor before: Yuan Changbing

TR01 Transfer of patent right

Effective date of registration: 20170526

Address after: 414501, Sichuan Province, Yueyang City, Pingjiang County town of Hunan stability cross Sichuan village

Patentee after: VPI MICA INSULATING MATERIALS CO., LTD., PINGJIANG

Address before: 510640 unit 371-1, public education building, 2414-2416, No. five, Tianhe District, Guangzhou, Guangdong

Patentee before: Guangdong Gaohang Intellectual Property Operation Co., Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Powdery mica foaming agent

Effective date of registration: 20171013

Granted publication date: 20141105

Pledgee: Pingjiang, Hunan, Hsbc Rural Bank Co

Pledgor: VPI MICA INSULATING MATERIALS CO., LTD., PINGJIANG

Registration number: 2017430000073

PE01 Entry into force of the registration of the contract for pledge of patent right
TR01 Transfer of patent right

Effective date of registration: 20191227

Address after: 314300 no.413, Daifeng Road, Wanghai street, Haiyan County, Jiaxing City, Zhejiang Province

Patentee after: Zhejiang Shengshi Ruijin Fastener Co., Ltd

Address before: 414501, Sichuan Province, Yueyang City, Pingjiang County town of Hunan stability cross Sichuan village

Patentee before: VPI MICA INSULATING MATERIALS CO., LTD., PINGJIANG

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20201228

Address after: Group 1, Xintan Zhenzi neighborhood committee, Sheyang County, Yancheng City, Jiangsu Province

Patentee after: Zheng Zonghua

Address before: No. 3144130, HaiHai Road, WangYan County, Zhejiang Province

Patentee before: Zhejiang Shengshi Ruijin Fastener Co.,Ltd.

TR01 Transfer of patent right
pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy