CN102863242A - Attapulgite volcaniclastic rock heat insulation raw material powder - Google Patents
Attapulgite volcaniclastic rock heat insulation raw material powder Download PDFInfo
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- CN102863242A CN102863242A CN2012103731832A CN201210373183A CN102863242A CN 102863242 A CN102863242 A CN 102863242A CN 2012103731832 A CN2012103731832 A CN 2012103731832A CN 201210373183 A CN201210373183 A CN 201210373183A CN 102863242 A CN102863242 A CN 102863242A
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- Prior art keywords
- heat insulation
- attapulgite
- insulation raw
- raw material
- material powder
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Links
- 229960000892 attapulgite Drugs 0.000 title claims abstract description 70
- 229910052625 palygorskite Inorganic materials 0.000 title claims abstract description 70
- 239000011435 rock Substances 0.000 title claims abstract description 58
- 239000000843 powder Substances 0.000 title claims abstract description 54
- 238000009413 insulation Methods 0.000 title claims abstract description 41
- 239000002994 raw material Substances 0.000 title abstract description 10
- 239000004927 clay Substances 0.000 claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 235000012054 meals Nutrition 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 2
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 7
- 239000002699 waste material Substances 0.000 abstract description 6
- 239000010451 perlite Substances 0.000 abstract description 2
- 235000019362 perlite Nutrition 0.000 abstract description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 238000004079 fireproofing Methods 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 238000005065 mining Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- -1 ore deposit Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 206010006895 Cachexia Diseases 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000004523 agglutinating effect Effects 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- CRPOUZQWHJYTMS-UHFFFAOYSA-N dialuminum;magnesium;disilicate Chemical compound [Mg+2].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] CRPOUZQWHJYTMS-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 208000016318 wasting Diseases 0.000 description 1
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The invention discloses an attapulgite volcaniclastic rock heat insulation raw material powder. The technical scheme is characterized in that the attapulgite volcaniclastic rock heat insulation raw material powder is composed of highly viscous attapulgite clay powders, attapulgite clay tailings, volcaniclastic rock mixtures, expanded perlite, diatom earth tailings and bentonite tailings. Materials of the attapulgite volcaniclastic rock heat insulation raw material powder are subjected to uniformly stirring and smashing, and then the materials are packaged to form a finished product of the attapulgite volcaniclastic rock heat insulation raw material powder. The attapulgite volcaniclastic rock heat insulation raw material powder has the advantages that the adhesive force is good, the attapulgite volcaniclastic rock heat insulation raw material powder is noise and heat insulating, fireproofing and flame retardant, a large number of various wastes are utilized in the materials of the attapulgite volcaniclastic rock heat insulation raw material powder, the resource utilization rate is increased, waste materials are changed into valuable things, the occupied land is reduced, the environment is protected and purified, the energy is saved, the production cost is lowered, the economic benefits are improved, and the attapulgite volcaniclastic rock heat insulation raw material powder is suitable for refractory and heat insulation concrete and refractory and heat insulation construction building.
Description
Technical field
The present invention relates to refractory materials, be specifically related to the heat insulation raw meal powder of a kind of Attapulgite volcanoclastic rock.
Background technology
The refractory materials kind is a lot, forms main minute six classes: soil, stone, sand, ore deposit, powder and other materials.
Mineral Resources in China 80% is intergrowth mineral, and a large amount of valuable resources retain among mine tailing, and tailings impoundment need to take a large amount of soils.A lot of Tailings Dams exceed the time limit or excess load is used, and even violation operation, make Tailings Dam have great potential safety hazard, and people's property and the life security of surrounding area caused to serious threat.
Attapulgite clay, except containing attapulgite, often contains the mineral such as wilkinite, kaolinite, hydromica, sepiolite, quartz, opal and carbonate.
With the volcanoclastic rock that also has of attapulgite clay ore deposit symbiosis, volcanoclastic rock is mostly on the upper strata in attapulgite clay ore deposit, the volcanoclastic rock ore bed on upper strata, some attapulgite clays mining area
'sthickness is up to tens of rice, at attapulgite clay in recovery process, the volcanoclastic rock on upper strata, attapulgite clay mining area is abandoned as waste, investigates factually, 1 ton of attapulgite clay of every exploitation, the volcanoclastic rock produced has more than 30 tons, by the output of producing 150000 tons per year, calculate, the volcanoclastic rock of generation, up to 4,500,000 tons, all can be utilized for many years, whole mining area is the volcanoclastic rock mixture of again piling up everywhere, causes the serious wasting of resources and financial loss.
Summary of the invention
The objective of the invention is to overcome weak point in prior art, provide a kind of Attapulgite volcanoclastic rock heat insulation raw meal powder.
The heat insulation raw meal powder of Attapulgite volcanoclastic rock is comprised of the sticky attapulgite clay powder of height, attapulgite clay mine tailing, volcanoclastic rock mixture, pearlstone, diatomite mine tailing and wilkinite mine tailing.
The production method of the heat insulation raw meal powder of Attapulgite volcanoclastic rock: the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock is stirred and pulverized, be packaged as the finished product of the heat insulation raw meal powder of Attapulgite volcanoclastic rock.
Attapulgite clay be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, attapulgite clay soil property exquisiteness, water-absorbent is strong, when wet, tool viscosity and plasticity-, be conducive to the bonding between raw material.
High sticky attapulgite clay powder refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, under the rotating speed of 11000 rev/mins, stir 20 minutes, to pour in the beaker of 250ml through the high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to be tested its suspension, tested viscosity value>=2200 into
mPasthe attapulgite clay powder be high sticky attapulgite clay powder, the height that the present invention selects glues attapulgite clay powder particles fineness≤0.074 millimeter.
Attapulgite clay can mix in recovery process a certain amount of rubble and earth, as a kind of mine tailing, abandons, and causes a large amount of wastings of resources, and the present invention selects the particle fineness of attapulgite clay mine tailing≤2.0 millimeters.
Volcanoclastic rock is the rock of the transitional type between magma lava and sedimentogeneous rock, wherein the composition more than 50% is comprised of the material of pyroclastic flow ejection, and these tephras are mainly the lava of premature coagulation on volcano, the rock formation that passage is burst on every side when volcanic eruption.The volcanoclastic rock mixture comprises landwaste, brilliant bits, glassiness bits, slurry bits, volcanic block (diameter is greater than 100 millimeters), volcanic gravel (diameter is greater than 2 millimeters) and volcanic ash (diameter is less than 2 millimeters), the volcanoclastic rock main chemical compositions is silicon-dioxide and aluminum oxide, have fire performance preferably, the present invention selects the particle fineness of volcanoclastic rock mixture≤5.0 millimeters.
Pearlstone be perlite ore through preheating, the material of the white granular that a kind of inside of making after the TRANSIENT HIGH TEMPERATURE calcining expansion is polynuclear plane.The characteristics such as pearlstone has that apparent density is light, thermal conductivity is low, chemical stability is good, the use temperature scope is wide, wettability power is little, nontoxic, tasteless, fire prevention and sound-absorbing, the present invention selects the particle fineness of pearlstone≤2.0 millimeters.
Diatomite is fine and smooth, loose, light weight, porous, specific surface area is large, space is regular distribution, and stable chemical nature is a kind of natural nano aperture amorphous silicon material, but diatomite is made a low multiple use, the product of most enterprises comes from one-level soil, and two, three grades of soil are discarded in a large number, have caused serious waste of resources, also polluted environment, the present invention selects the particle fineness of diatomite mine tailing≤2.0 millimeters.
The rock that wilkinite mainly is comprised of montmorillonite, it is the important raw mineral materials of field of metallurgy, the wilkinite mine tailing that the present invention selects is distributed in the lower floor in attapulgite clay ore deposit mostly, be difficult to carry out independent exploitation, but the content of aluminum oxide >=16% in the wilkinite mine tailing, and thering is plasticity-and agglutinating value(of coal), the present invention selects the particle fineness of wilkinite mine tailing≤2.0 millimeters.
The present invention is achieved by following technical proposals:
1, the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock is comprised of following component by weight percentage: high sticky attapulgite clay powder 2～15%, attapulgite clay mine tailing 5～25%, volcanoclastic rock mixture 10～40%, pearlstone 5～40%, diatomite mine tailing 2～15% and wilkinite mine tailing 2～15%;
The production method of the heat insulation raw meal powder of described Attapulgite volcanoclastic rock: the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock is added in the two shaft pugmill mixer moved and stirs, stirring, to pulverize in rear input pulverizer be the work in-process of the heat insulation raw meal powder of Attapulgite volcanoclastic rock, the half-finished particle fineness of the heat insulation raw meal powder of Attapulgite volcanoclastic rock≤0.15 millimeter, be packaged as the finished product of the heat insulation raw meal powder of Attapulgite volcanoclastic rock.
The heat insulation raw meal powder of Attapulgite volcanoclastic rock has that sticking power is good, the characteristics of sound-insulating and heat-insulating and fire protection flame retarding.
In the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock, the various wastes of a large amount of employing, not only be conducive to improve resource utilization, turns waste into wealth, and can also reduce land occupation, and protection and environment purification are saved the energy, reduce production costs, and increase economic efficiency.
The heat insulation raw meal powder of Attapulgite volcanoclastic rock is applicable to the fire-proof and thermal-insulation concrete and builds the insulating refractory engineering by laying bricks or stones.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock is comprised of following component by weight percentage: high sticky attapulgite clay powder 8%, attapulgite clay mine tailing 12%, volcanoclastic rock mixture 32%, pearlstone 30%, diatomite mine tailing 10% and wilkinite mine tailing 8%;
The production method of the heat insulation raw meal powder of described Attapulgite volcanoclastic rock: the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock is added in the two shaft pugmill mixer moved and stirs, stirring, to pulverize in rear input pulverizer be the work in-process of the heat insulation raw meal powder of Attapulgite volcanoclastic rock, the half-finished particle fineness of the heat insulation raw meal powder of Attapulgite volcanoclastic rock≤0.105 millimeter, be packaged as the finished product of the heat insulation raw meal powder of Attapulgite volcanoclastic rock.
Claims (1)
1. the heat insulation raw meal powder of Attapulgite volcanoclastic rock, it is characterized in that, the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock is comprised of following component by weight percentage: high sticky attapulgite clay powder 2～15%, attapulgite clay mine tailing 5～25%, volcanoclastic rock mixture 10～40%, pearlstone 5～40%, diatomite mine tailing 2～15% and wilkinite mine tailing 2～15%;
The production method of the heat insulation raw meal powder of described Attapulgite volcanoclastic rock: the batching of the heat insulation raw meal powder of Attapulgite volcanoclastic rock is added in the two shaft pugmill mixer moved and stirs, stirring, to pulverize in rear input pulverizer be the work in-process of the heat insulation raw meal powder of Attapulgite volcanoclastic rock, the half-finished particle fineness of the heat insulation raw meal powder of Attapulgite volcanoclastic rock≤0.15 millimeter, be packaged as the finished product of the heat insulation raw meal powder of Attapulgite volcanoclastic rock;
The sticky attapulgite clay powder of described height refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, under the rotating speed of 11000 rev/mins, stir 20 minutes, to pour in the beaker of 250ml through the high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to be tested its suspension, tested viscosity value>=2200 into
mPasthe attapulgite clay powder be high sticky attapulgite clay powder, the height that the present invention selects glues attapulgite clay powder particles fineness≤0.074 millimeter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103731832A CN102863242B (en) | 2012-09-30 | 2012-09-30 | Attapulgite volcaniclastic rock heat insulation raw material powder |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103731832A CN102863242B (en) | 2012-09-30 | 2012-09-30 | Attapulgite volcaniclastic rock heat insulation raw material powder |
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| Publication Number | Publication Date |
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| CN102863242A true CN102863242A (en) | 2013-01-09 |
| CN102863242B CN102863242B (en) | 2013-12-11 |
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| CN2012103731832A Expired - Fee Related CN102863242B (en) | 2012-09-30 | 2012-09-30 | Attapulgite volcaniclastic rock heat insulation raw material powder |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265211A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Flame-retardant foaming agent of pyroclastic rocks |
| CN103265214A (en) * | 2013-05-27 | 2013-08-28 | 许盛英 | Powdery bentonite foamer |
| CN103265221A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Powdery basalt foaming agent |
| CN103265210A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Mica flame retardant foaming agent |
| CN103265215A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Powdery phosphogypsum foaming agent |
| CN103265219A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Powdery quicklime foaming agent |
| CN103265208A (en) * | 2013-05-27 | 2013-08-28 | 许盛英 | Pumice flame-retardant foaming agent |
| CN103265212A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Tailings antiflaming foaming agent |
| CN104649647A (en) * | 2013-11-20 | 2015-05-27 | 深圳市格林美高新技术股份有限公司 | High-temperature-resistant thermal-insulation material prepared with industrial tailings and preparation method thereof |
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| CN101007718A (en) * | 2007-01-29 | 2007-08-01 | 袁长兵 | Attapulgite insulated brick for sun-light green-house |
| CN101348626A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Temperature-regulating paint and preparation method thereof |
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2012
- 2012-09-30 CN CN2012103731832A patent/CN102863242B/en not_active Expired - Fee Related
Patent Citations (5)
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| JPH10231166A (en) * | 1997-02-18 | 1998-09-02 | Tokyo Yogyo Co Ltd | Baked building material block utilizing waste |
| CN101007718A (en) * | 2007-01-29 | 2007-08-01 | 袁长兵 | Attapulgite insulated brick for sun-light green-house |
| CN101348626A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Temperature-regulating paint and preparation method thereof |
| CN102503490A (en) * | 2011-11-10 | 2012-06-20 | 许庆华 | Baking-free gravel attapulgite fire-retarding ceramsite |
| CN102503323A (en) * | 2011-11-10 | 2012-06-20 | 许庆华 | Baking-free cylindrical attapulgite fire-retarding ceramsite |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265208B (en) * | 2013-05-27 | 2014-12-10 | 许盛英 | Pumice flame-retardant foaming agent |
| CN103265214A (en) * | 2013-05-27 | 2013-08-28 | 许盛英 | Powdery bentonite foamer |
| CN103265208A (en) * | 2013-05-27 | 2013-08-28 | 许盛英 | Pumice flame-retardant foaming agent |
| CN103265210B (en) * | 2013-06-07 | 2014-12-10 | 许盛英 | Mica flame retardant foaming agent |
| CN103265215A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Powdery phosphogypsum foaming agent |
| CN103265219A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Powdery quicklime foaming agent |
| CN103265210A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Mica flame retardant foaming agent |
| CN103265215B (en) * | 2013-06-07 | 2014-12-10 | 许盛英 | Powdery phosphogypsum foaming agent |
| CN103265221A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Powdery basalt foaming agent |
| CN103265211A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Flame-retardant foaming agent of pyroclastic rocks |
| CN103265212A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Tailings antiflaming foaming agent |
| CN103265212B (en) * | 2013-06-07 | 2014-12-10 | 许盛英 | Tailings antiflaming foaming agent |
| CN103265219B (en) * | 2013-06-07 | 2014-12-10 | 许盛英 | Powdery quicklime foaming agent |
| CN104649647A (en) * | 2013-11-20 | 2015-05-27 | 深圳市格林美高新技术股份有限公司 | High-temperature-resistant thermal-insulation material prepared with industrial tailings and preparation method thereof |
| CN104649647B (en) * | 2013-11-20 | 2016-08-17 | 深圳市格林美高新技术股份有限公司 | A kind of thermostable heat-isolating material utilizing industrial tailings and preparation method thereof |
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| CN102863242B (en) | 2013-12-11 |
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