Gold(I) fluoride

Gold(I) fluoride
Identifiers
3D model (JSmol)	Interactive image;
ChemSpider	10605696 ;
PubChem CID	21225580;
CompTox Dashboard (EPA)	DTXSID401030369 ;
	InChI InChI=1S/Au.FH/h;1H/q+1;/p-1 Key: SDQPNEPNURFLTA-UHFFFAOYSA-M ;
	SMILES [Au]F;
Properties
Chemical formula	AuF
Molar mass	215.964973 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Gold(I) fluoride is the inorganic compound with the formula Au F. The solid has eluded isolation, but its existence has been observed by rotational spectroscopy^[1] and mass spectrometry as a gas.^[2]

When stabilized by an NHC ligand, a gold fluoride complex has been characterized.^[3]

References

^ Evans, Corey J.; Gerry, Michael C. L. (2000). "Confirmation of the Existence of Gold(I) Fluoride, AuF: Microwave Spectrum and Structure". Journal of the American Chemical Society. 122 (7): 1560. doi:10.1021/ja9938985.
^ Schröder, Detlef; Hrušák, Jan; Tornieporth-Oetting, Inis C.; Klapötke, Thomas M.; Schwarz, Helmut (1994). "Neutral Gold(I) Fluoride Does Indeed Exist". Angewandte Chemie International Edition in English. 33 (2): 212. doi:10.1002/anie.199402121.
^ David S. Laitar; Peter Müller; Thomas G. Gray; Joseph P. Sadighi (2005). "A Carbene-Stabilized Gold(I) Fluoride: Synthesis and Theory". Organometallics. 24 (19): 4503–4505. doi:10.1021/om050619f.

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[1] Evans, Corey J.; Gerry, Michael C. L. (2000). "Confirmation of the Existence of Gold(I) Fluoride, AuF: Microwave Spectrum and Structure". Journal of the American Chemical Society. 122 (7): 1560. doi:10.1021/ja9938985.

[2] Schröder, Detlef; Hrušák, Jan; Tornieporth-Oetting, Inis C.; Klapötke, Thomas M.; Schwarz, Helmut (1994). "Neutral Gold(I) Fluoride Does Indeed Exist". Angewandte Chemie International Edition in English. 33 (2): 212. doi:10.1002/anie.199402121.

[3] David S. Laitar; Peter Müller; Thomas G. Gray; Joseph P. Sadighi (2005). "A Carbene-Stabilized Gold(I) Fluoride: Synthesis and Theory". Organometallics. 24 (19): 4503–4505. doi:10.1021/om050619f.

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References

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