SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 2.

1 (06/08/2020) - Page 1/8

PT. GLOBAL MEDIPRO INVESTAMA
METRACIDE - SIMLQ06

SAFETY DATA SHEET

(REACH regulation (EC) n° 1907/2006 - n° 2015/830)

SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier
Product name : METRACIDE
Product code : SIMLQ06.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Biocidal product.
1.3. Details of the supplier of the safety data sheet
Registered company name : PT. GLOBAL MEDIPRO INVESTAMA.
Address : Jalan Penjernihan 1 No. 3 - Bendungan hilir.10210.Jakarta Pusat..
Telephone : +62 21 5722593. Fax : +62 21 57974359.
Nom de la Personne Responsable : Mr Askar HARIS (factory manager)
1.4. Emergency telephone number : .
Association/Organisation : .

SECTION 2 : HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture
In compliance with EC regulation No. 1272/2008 and its amendments.
Acute oral toxicity, Category 4 (Acute Tox. 4, H302).
Acute inhalation toxicity, Category 4 (Acute Tox. 4, H332).
Skin corrosion, Category 1B (Skin Corr. 1B, H314).
Serious eye damage, Category 1 (Eye Dam. 1, H318).
Respiratory sensitisation, Category 1 (Resp. Sens. 1, H334).
Skin sensitisation, Category 1 (Skin Sens. 1, H317).
Specific target organ toxicity (single exposure), Category 2 (STOT SE 2, H371).
Specific target organ toxicity (single exposure), Category 3 (STOT SE 3, H335).
This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.
This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard conditions of use.
2.2. Label elements
Biocidal mixture (see section 15).
In compliance with EC regulation No. 1272/2008 and its amendments.
Hazard pictograms :

GHS05 GHS07 GHS08

Signal Word :
DANGER
Product identifiers :
EC 203-856-5 GLUTARAL
603-001-00-X METHANOL
612-131-00-6 DIDECYLDIMETHYLAMMONIUM CHLORIDE
Hazard statements :
H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H371 May cause damage to organs (if inhaled, if swallowed, in contact with skin).
Precautionary statements - Prevention :
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
Precautionary statements - Response :
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

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P302 + P352 IF ON SKIN: Wash with plenty of water/...

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P311 IF exposed or concerned: Call a POISON CENTER/doctor/...
P310 Immediately call a POISON CENTER/doctor
P321 Specific treatment (see on this label).
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/...
P362 + P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
Precautionary statements - Disposal :
P501 Dispose of contents and container to in accordance with national regulation.
Other information :
2.3. Other hazards
The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European
CHemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table
The mixture fulfils neither the PBT nor the vPvB criteria for mixtures in accordance with annexe XIII of the REACH regulations EC 1907/2006.

SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures
Composition :
Identification (EC) 1272/2008 Note %
CAS: 111-30-8 GHS06, GHS08, GHS05, GHS09 [1] 2.5 <= x % < 10
EC: 203-856-5 Dgr
Acute Tox. 3, H331
GLUTARAL Acute Tox. 3, H301
Skin Corr. 1B, H314
Resp. Sens. 1, H334
Skin Sens. 1, H317
Aquatic Acute 1, H400
M Acute = 1
INDEX: 603-001-00-X GHS02, GHS06, GHS08 [1] 2.5 <= x % < 10
CAS: 67-56-1 Dgr
EC: 200-659-6 Flam. Liq. 2, H225
Acute Tox. 3, H331
METHANOL Acute Tox. 3, H311
Acute Tox. 3, H301
STOT SE 1, H370
INDEX: 612-131-00-6 GHS05, GHS07 1 <= x % < 2.5
CAS: 7173-51-5 Dgr
EC: 230-525-2 Acute Tox. 4, H302
Skin Corr. 1B, H314
DIDECYLDIMETHYLAMMONIUM CHLORIDE
INDEX: 603-002-00-5 GHS02 [1] 0 <= x % < 1
CAS: 64-17-5 Dgr
EC: 200-578-6 Flam. Liq. 2, H225
REACH: 01-2119457610-43

ETHANOL
INDEX: 011-002-00-6 GHS05 [1] 0 <= x % < 1
CAS: 1310-73-2 Dgr
EC: 215-185-5 Skin Corr. 1A, H314
REACH: 01-2119457892-27-XXXX

SODIUM HYDROXIDE
(Full text of H-phrases: see section 16)
Information on ingredients :
[1] Substance for which maximum workplace exposure limits are available.

SECTION 4 : FIRST AID MEASURES

As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing by an unconscious person.
4.1. Description of first aid measures
In the event of exposure by inhalation :
In the event of massive inhalation, remove the person exposed to fresh air. Keep warm and at rest.
If the person is unconscious, place in recovery position. Notify a doctor in all events, to ascertain whether observation and supportive hospital
care will be necessary.
If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.

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Do not proceed with mouth-to-mouth or mouth-to-nose resuscitation.Use the appropriate equipment.

In the event of an allergic reaction, seek medical attention.
In the event of splashes or contact with eyes :
Wash thoroughly with fresh, clean water for 15 minutes holding the eyelids open.
Regardless of the initial state, refer the patient to an ophthalmologist and show him the label.
In the event of splashes or contact with skin :
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
Remove any soiled or splashed clothing immediately.
Watch out for any remaining product between skin and clothing, watches, shoes, etc.
In the event of an allergic reaction, seek medical attention.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.
In the event of swallowing :
Do not give the patient anything orally.
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water, administer activated medical charcoal
and consult a doctor.
Seek medical attention immediately, showing the label.
If swallowed accidentally, call a doctor to ascertain whether observation and hospital care will be necessary. Show the label.
4.2. Most important symptoms and effects, both acute and delayed
No data available.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.

SECTION 5 : FIREFIGHTING MEASURES

Non-flammable.
5.1. Extinguishing media
No data available.
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
In the event of a fire, the following may be formed :
- carbon monoxide (CO)
- carbon dioxide (CO2)
5.3. Advice for firefighters
No data available.

SECTION 6 : ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Consult the safety measures listed under headings 7 and 8.
For non first aid worker
Avoid inhaling the vapors.
Avoid any contact with the skin and eyes.
If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety apparatus.
For first aid worker
First aid workers will be equipped with suitable personal protective equipment (See section 8).
6.2. Environmental precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums
for waste disposal.
Prevent any material from entering drains or waterways.
6.3. Methods and material for containment and cleaning up
If the ground is contaminated, once the product has been recovered by sponging with an inert and non-combustible absorbent material, wash the
contaminated area in plenty of water.
Clean preferably with a detergent, do not use solvents.
6.4. Reference to other sections
No data available.

SECTION 7 : HANDLING AND STORAGE

Requirements relating to storage premises apply to all facilities where the mixture is handled.
Individuals with a history of asthma, allergies and/or chronic or periodical breathing difficulties should not, under any circumstances, use these
mixtures.
Individuals with a history of skin sensitisation should not, under any circumstance, handle this mixture.

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7.1. Precautions for safe handling

Always wash hands after handling.
Remove and wash contaminated clothing before re-using.
Emergency showers and eye wash stations will be required in facilities where the mixture is handled constantly.
Fire prevention :
Handle in well-ventilated areas.
Prevent access by unauthorised personnel.
Recommended equipment and procedures :
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations.
Do not inhale vapours.
Avoid inhaling vapors. Carry out any industrial operation which may give rise to this in a sealed apparatus.
Provide vapor extraction at the emission source and also general ventilation of the premises.
Also provide breathing apparatus for certain short tasks of an exceptional nature and for emergency interventions.
In all cases, recover emissions at source.
Avoid exposure - obtain special instructions before use.
Prohibited equipment and procedures :
No smoking, eating or drinking in areas where the mixture is used.
7.2. Conditions for safe storage, including any incompatibilities
No data available.
Storage
Keep the container tightly closed in a dry, well-ventilated place.
Keep away from food and drink, including those for animals.
Packaging
Always keep in packaging made of an identical material to the original.
7.3. Specific end use(s)
No data available.

SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters
Occupational exposure limits :
- European Union (2019/1831, 2017/2398, 2017/164, 2009/161, 2006/15/CE, 2000/39/CE, 98/24/CE) :
CAS VME-mg/m3 : VME-ppm : VLE-mg/m3 : VLE-ppm : Notes :
67-56-1 260 200 - - Peau
- ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0.05 ppm SEN; A4
67-56-1 200 ppm 250 ppm Skin; BEI
64-17-5 1000 ppm A3
1310-73-2 2 mg/m3
- Germany - AGW (BAuA - TRGS 900, 08/08/2019) :
CAS VME : VME : Excess Notes
111-30-8 0.05 ppm 2(I)
0.2 mg/m³
67-56-1 200 ppm 4(ΙΙ)
270 mg/m³
64-17-5 200 ppm 4(ΙΙ)
380 mg/m³
- France (INRS - ED984 / 2019-1487) :
CAS VME-ppm : VME-mg/m3 : VLE-ppm : VLE-mg/m3 : Notes : TMP No :
111-30-8 0.1 0.4 0.2 0.8 - 65.66
67-56-1 200 260 1000 1300 (12) 84
64-17-5 1000 1900 5000 9500 - 84
1310-73-2 - 2 - - - -
- UK / WEL (Workplace exposure limits, EH40/2005, 2011) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
111-30-8 0.05 ppm 0.05 ppm Sen
0.2 mg/m³ 0.2 mg/m³
67-56-1 200 ppm 250 ppm Sk
266 mg/m³ 333 mg/m³
64-17-5 1000 ppm - ppm
1920 mg/m³ - mg/m³
1310-73-2 - ppm - ppm
- mg/m³ 2 mg/m³

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8.2. Exposure controls

Personal protection measures, such as personal protective equipment
Use personal protective equipment that is clean and has been properly maintained.
Store personal protective equipment in a clean place, away from the work area.
Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation,
especially in confined areas.
- Eye / face protection
Avoid contact with eyes.
Use eye protectors designed to protect against liquid splashes
Before handling, wear safety goggles with protective sides accordance with standard EN166.
In the event of high danger, protect the face with a face shield.
Prescription glasses are not considered as protection.
Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours.
Provide eyewash stations in facilities where the product is handled constantly.
- Hand protection
Wear suitable protective gloves in the event of prolonged or repeated skin contact.
Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374.
Gloves must be selected according to the application and duration of use at the workstation.
Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled,
necessary physical protections (cutting, pricking, heat protection), level of dexterity required.
Type of gloves recommended :
- Natural latex
- Nitrile rubber (butadiene-acrylonitrile copolymer rubber (NBR))
- PVC (polyvinyl chloride)
- Butyl Rubber (Isobutylene-isoprene copolymer)
Recommended properties :
- Impervious gloves in accordance with standard EN374
- Body protection
Avoid skin contact.
Wear suitable protective clothing.
Suitable type of protective clothing :
In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent
skin contact.
In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact.
Wear suitable protective clothing and, in particular, an apron and boots. These items of clothing shall be maintained in good condition and
cleaned after use.
Work clothing worn by personnel shall be laundered regularly.
After contact with the product, all parts of the body that have been soiled must be washed.
- Respiratory protection
Avoid breathing vapours.
Avoid inhaling vapors. Carry out any industrial task giving rise to this risk in a closed circuit. Provide extractor fans to capture the vapors at the
emission source as well as general ventilation of the premises.
If the ventilation is insufficient, wear appropriate breathing apparatus.
When workers are confronted with concentrations that are above occupational exposure limits, they must wear a suitable, approved, respiratory
protection device.
Likewise provide safety breathing apparatus for certain short tasks of an exceptional nature or for emergency interventions
Anti-gas and vapour filter(s) (Combined filters) in accordance with standard EN14387 :
- A1 (Brown)
- A3 (Brown)

SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
General information :
Physical state : Fluid liquid.
Color: Blue
Odour: Typical.
Important health, safety and environmental information
pH : 6.00 +/- 0,3.
Neutral.
Boiling point/boiling range : Not specified.
Flash point interval : Not relevant.
Vapour pressure (50°C) : Not relevant.
Density : 1,02 +/- 0.03
Water solubility : Dilutable.

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Melting point/melting range : Not specified.

Self-ignition temperature : Not specified.
Decomposition point/decomposition range : Not specified.
9.2. Other information
No data available.

SECTION 10 : STABILITY AND REACTIVITY

10.1. Reactivity
No data available.
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
Avoid :
- frost
10.5. Incompatible materials
No data available.
10.6. Hazardous decomposition products
The thermal decomposition may release/form :
- carbon monoxide (CO)
- carbon dioxide (CO2)

SECTION 11 : TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
Harmful if swallowed.
Harmful by inhalation.
May cause irreversible damage to the skin; namely, visible necrosis through the epidermis and into the dermis, following exposure between three
minutes and one hour.
Corrosive reactions are typified by ulcers, bleeding, bloody scabs, and, by the end of observation at 14 days, by discolouration due to blanching
of the skin, complete areas of alopecia, and scars.
Respiratory tract irritation may occur, together with symptoms such as coughing, choking and breathing difficulties.
May cause hypersensitivity of the respiratory tracts with effects taking the form of asthma, rhinitis/conjunctivitis or alveolitis.
May cause an allergic reaction by skin contact.
May cause damage to organs.
11.1.1. Substances
No toxicological data available for the substances.
11.1.2. Mixture
Respiratory or skin sensitisation :
May cause allergy or asthma symptoms or breathing difficulties if inhaled.

SECTION 12 : ECOLOGICAL INFORMATION

12.1. Toxicity
12.1.2. Mixtures
No aquatic toxicity data available for the mixture.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
No data available.
12.6. Other adverse effects
No data available.

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SECTION 13 : DISPOSAL CONSIDERATIONS

Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
13.1. Waste treatment methods
Do not pour into drains or waterways.
Waste :
Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water,
air, soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging :
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.

SECTION 14 : TRANSPORT INFORMATION

Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR 2019 -
IMDG 2018 - ICAO/IATA 2020).
14.1. UN number
1760
14.2. UN proper shipping name
UN1760=CORROSIVE LIQUID, N.O.S.
(glutaral)
14.3. Transport hazard class(es)
- Classification :

8
14.4. Packing group
II
14.5. Environmental hazards
-
14.6. Special precautions for user

ADR/RID Class Code Pack gr. Label Ident. LQ Provis. EQ Cat. Tunnel
8 C9 II 8 80 1L 274 E2 2 E

IMDG Class 2°Label Pack gr. LQ EMS Provis. EQ Stowage Segregation

Handling
8 - II 1L F-A, S-B 274 E2 Category B -
SW2

IATA Class 2°Label Pack gr. Passager Passager Cargo Cargo note EQ
8 - II 851 1L 855 30 L A3 A803 E2
8 - II Y840 0.5 L - - A3 A803 E2
For limited quantities, see part 2.7 of the OACI/IATA and chapter 3.4 of the ADR and IMDG.
For excepted quantities, see part 2.6 of the OACI/IATA and chapter 3.5 of the ADR and IMDG.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
No data available.

SECTION 15 : REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Classification and labelling information included in section 2:
The following regulations have been used:
- EU Regulation No. 1272/2008 amended by EU Regulation No. 2020/217 (ATP 14)
- Container information:
No data available.
- Particular provisions :
No data available.

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- Labelling for biocidal products (Regulation 1896/2000, 1687/2002, 2032/2003, 1048/2005, 1849/2006, 1451/2007 and Directive 98/8/EC)
:
Name CAS % Product-type
DIDECYLDIMETHYLAMMONIUM CHLORIDE 7173-51-5 20.00 g/kg 02
GLUTARAL 111-30-8 85.00 g/kg 02
Product-type 2 : Disinfectants and algaecides not intended for direct application to humans or animals.
- Standardised American system for the identification of hazards presented by the product in view of emergency procedures (NFPA 704)
:
NFPA 704, Labelling: Health=3 Inflammability=1 Instability/Reactivity=1 Specific Risk=none

3 1

- Swiss ordinance on the incentive tax on volatile organic compounds :

64-17-5 éthanol, seulement s’il s’agit d’alcools impropres à la consommation (art. 31 de la loi fédérale sur l’alcool)
67-56-1 méthanol (alcool méthylique)
15.2. Chemical safety assessment
No data available.

SECTION 16 : OTHER INFORMATION

Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of
knowledge and on national and community regulations.
The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.
The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a
guarantee of the properties thereof.
Wording of the phrases mentioned in section 3 :
H225 Highly flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H370 Causes damage to organs .
H400 Very toxic to aquatic life.
Abbreviations :
ADR : European agreement concerning the international carriage of dangerous goods by Road.
IMDG : International Maritime Dangerous Goods.
IATA : International Air Transport Association.
ICAO : International Civil Aviation Organisation
RID : Regulations concerning the International carriage of Dangerous goods by rail.
GHS05 : Corrosion
GHS07 : Exclamation mark
GHS08 : Health hazard
PBT: Persistent, bioaccumulable and toxic.
vPvB : Very persistent, very bioaccumulable.
SVHC : Substances of very high concern.

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