Safety Data Sheet CB-9099

Supercedes Date 05/07/2015 Issuing Date 11/12/2015

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name CB-9099 Product Code APM_467C-SG
Recommended Use Biocidal product Chemical Nature Solid
Manufacturer, Importer, Supplier Supplier
NCH CORPORATION NCH Singapore Pte. Ltd.
BOX 152170 1100 Lower Delta Road #03-02 EPL Building,
Irving, TX 75015 Singapore 169206
Telephone Inquiry Telephone Inquiry
972-579-2477 +65-6743 9122
Emergency Telephone Number Emergency Telephone Number
CHEMTREC® 800-424-9300 +65-6743 9122
Fax Number Fax Number
972-438-0999 +65-6745 7266

2. HAZARD IDENTIFICATION
Color White Physical state Solid Odor Slight Chlorine

GHS
Classification
Physical Hazards
None
Health Hazard
Acute Oral Toxicity Category 4
Acute Dermal Toxicity Category 4
Acute Inhalation Toxicity - Vapors Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 5
Serious Eye Damage/Eye Irritation Category 2
Specific target organ systemic toxicity (single exposure) Category 3
Acute Aquatic Toxicity Category 1
Chronic Aquatic Toxicity Category 1

Other +azards
None

Labeling
Signal Word
WARNING

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Hazard 6tatements Precautionary Statements

H302 - Harmful if swallowed P261 - Avoid breathing dust/fume/gas/mist/vapours/spray
H312 - Harmful in contact with skin P264 - Wash face, hands and any exposed skin thoroughly after handling
H319 - Causes serious eye irritation P270 - Do not eat, drink or smoke when using this product
H332 - Harmful if inhaled P271 - Use in a well-ventilated area.
H335 - May cause respiratory irritation P273 - Avoid release to the environment
H410 - Very toxic to aquatic life with long lasting effects P280 - Wear protective gloves, protective clothing and eye protection.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P312 - Call a physician if unwell.
P322 - Specific measures (see supplemental first aid instructions on this label)
P330 - Rinse mouth
P363 - Wash contaminated clothing before reuse
P302+ P350 - IF ON SKIN: Gently wash with plenty of soap and water
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P301+ P312 - IF SWALLOWED: Call a physician if unwell
P304 + P312 - IF INHALED: Call a POISON CENTER or doctor/physician if you
feel unwell
P304 + P340 - IF INHALED: Remove person to fresh air and keep at rest in a
position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337 + P313 - If eye irritation persists, get medical attention.
P405 - Store locked up
P501 - Dispose of contents and container to an approved waste disposal plant.
P391 - Collect spillage

0 % of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION AND INFORMATION ON INGREDIENTS

Component CAS No. Weight %
TRICHLORO-S-TRIAZINETRIONE 87-90-1 99-100
The product contains no substances which at their given concentration, are considered to be hazardous to health.

4. FIRST AID MEASURES

General Advice Do not get in eyes, on skin or on clothing. Do not breathe dust or fume.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses. Call a physician or poison control center immediately.
Skin Contact Take off all contaminated clothing immediately. Wash off immediately with plenty of water
for at least 15 minutes. Call a physician or poison control center immediately.
Inhalation Move to fresh air. If breathing has stopped, apply artificial respiration. Call a physician or
poison control center immediately.
Ingestion Rinse mouth.
Notes to Physician The product causes burns of eyes, skin and mucous membranes. Control of circulatory
system, shock therapy if needed.

5. FIRE-FIGHTING MEASURES
Flash Point Not flammable Method Not applicable
Autoignition Temperature
No information available.
Flammability Limits in Air %: Not applicable. Upper No data available Lower No data available
Suitable Extinguishing Media
Water spray.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating gases and vapors.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, NOHSC (approved or equivalent) and full protective
gear.

NFPA Health 3 Flammability 0 Instability 2

HMIS Health 3 Flammability 0 Instability 2

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6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Prevent further leakage or
spillage if safe to do so.
Environmental Precautions Do not flush into surface water or sanitary sewer system.
Methods for Containment Pick up and arrange disposal without creating dust.
Methods for Cleaning Up Use clean non-sparking tools to collect material and place it into loosely covered plastic
containers for later disposal.
Neutralizing Agent Not applicable.

7. HANDLING AND STORAGE

Handling Wear personal protective equipment.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors/dust.
Storage Store in original container.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Protect from moisture.
Storage Temperature Minimum 0°C Maximum 52°C
Storage Conditions Indoor X Outdoor Heated Refrigerated

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines
Engineering Measures Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined
areas.
Personal Protective Equipment
Respiratory Protection Respirator must be worn if exposed to dust.
Eye/Face Protection Tightly fitting safety goggles. Face-shield.
Hand Protection Protective gloves.
Skin Protection Wear suitable protective clothing, Impervious gloves.
General Hygiene Considerations Do not eat, drink or smoke when using this product. Remove and wash contaminated
clothing before re-use.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Textured white solid
Color White
Physical state Solid
Odor Slight chlorine
Odor Threshold No data available
pH (as 1% solution) 2.5
Melting Point/Range No data available
Freezing Point No information available
Boiling Point/Range No information available
Flash Point Not flammable
Method Not applicable
Evaporation Rate No information available
Vapor Pressure No information available
Solubility Completely soluble
Vapor Density No information available
Specific Gravity 1.2-1.9
Autoignition Temperature No information available
Viscosity Tablets
Molecular Weight No data available
Percent Volatile (Volume) 0
VOC Content (%) 0
VOC Content (g/L) 0
Flammability Limits in Air %: Not applicable
Upper No data available
Lower No data available
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Partition Coefficient (n-octanol/water) No data available

Decomposition temperature °C No information available

10. STABILITY AND REACTIVITY

Reactivity Hazardous polymerization does not occur.
Chemical Stability Stable. Hazardous polymerization does not occur.
Possibility of Hazardous Reactions None under normal processing.
Conditions to Avoid Heat, flames, and sparks, Protect from moisture.
Incompatible Products Strong oxidizing agents, Reducing agents, Acids, Bases,
Ammonia, Calcium hypochlorite.
Hazardous Decomposition Products Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas,
Chlorine, Hydrogen bromide, Bromine, Phosgene, Sodium
oxides.

11. TOXICOLOGICAL INFORMATION

Product Information
Principle Route of Exposure Skin contact, Eye contact, Inhalation.

The following values are calculated based on chapter 3.1 of the GHS document
Oral LD50 No information available
Dermal LD50 No information available
Inhalation LC50
Gas Not applicable
Mist Not applicable
Vapor Not applicable
Primary Routes of Entry Inhalation, Ingestion.
Main Symptoms
Acute Effects
Eyes Corrosive to the eyes and may cause severe damage including blindness.
Skin Causes skin burns.
Inhalation Harmful by inhalation. Causes burns.
Ingestion If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the
esophagus and the stomach. May cause central nervous system effects such as headache,
dizziness, weakness, staggering gait, nausea, blurred vision, excitation, and in extreme
cases, coma or death.
Chronic Effects Inhaled corrosive substances can lead to a toxic edema of the lungs, Liver and kidney
injuries may occur.
Target Organ Effects Central nervous system, Liver, Kidney, Bladder, Cardiovascular system.
Aggravated Medical Conditions Respiratory disorders, Skin disorders, Kidney disorders.

Component Information
Acute Toxicity
Component Oral LD50 Dermal LD50 Inhalation LC50 Draize Test Other
TRICHLORO-S-TRIAZINET = 406 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit > 50 mg/L ( Rat ) 1 h no data available no data available
RIONE )
Chronic Toxicity
Carcinogenicity There are no known carcinogenic chemicals in this product.

12. ECOLOGICAL INFORMATION

Product Information No data available
Component Information
Component Toxicity to Algae Toxicity to Fish Microtox Crustacea log Pow
TRICHLORO-S-TRIAZINETRI Not applicable LC50 0.06 - 0.11 mg/L no data available 0.21: 48 h Daphnia N/A
ONE Oncorhynchus mykiss 96 h magna mg/L EC50
LC50 0.13 - 0.5 mg/L Lepomis 0.16 - 0.18: 48 h
macrochirus 96 h Daphnia magna mg/L
EC50 Static

Ecotoxicity Effects No information available

Persistence and Degradability No information available
Bioaccumulation No information available

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Mobility No information available

13. DISPOSAL INFORMATION

Product Disposal Dispose of contents/container in accordance with local regulation.
Container Disposal Empty containers should be taken for local recycling, recovery, or waste disposal. Do not
re-use empty containers.

14. TRANSPORTATION INFORMATION

ADR / RID
UN-No UN2465
Hazard Class 5.1
Packing Group II
Proper Shipping Name Dichloroisocyanuric acid salts, mixture
Classification Code O2
Limited Quantity 500 g

IMDG/IMO
UN-No UN2465
Hazard Class 5.1
Packing Group II
Proper Shipping Name Dichloroisocyanuric acid salts, mixture
EmS No. F-A, S-Q
Description UN2465, Dichloroisocyanuric acid salts, mixture,5.1,PG II

IATA
UN-No UN2465
Hazard Class 5.1
Packing Group II
Proper Shipping Name Dichloroisocyanuric acid salts, mixture
Precautionary Statements - 5L
Response
Shipping Description UN2465,Dichloroisocyanuric acid salts, mixture,5.1,PG II

15. REGULATORY INFORMATION

International Regulations:

Malaysia:
This Safety Data Sheet is prepared according to the requirement of Occupational Safety and Health (Classification, Labeling and Safety Data Sheet
of Hazardous Chemicals), Regulations CLASS 2013.

Singapore:

Workplace Safety and Health Act & Workplace Safety and Health (General Provisions) Regulations:
This product is subject to the SDS, labeling, PEL and other requirements in the Act/Regulations.

Environmental Protections and Management Act & Environmental Protection and Management (Hazardous Substance) Regulations:
This product is subject to the requirements in the Act/Regulations.

16. OTHER INFORMATION

Prepared By Anne Ooi
Reason for Revision No information available.
Glossary No information available.
List of References. No information available.

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CHEM-AQUA DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use,
storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with
such unrecommended use, storage or disposal of the product. The information provided on this document is correct to the
best of our knowledge, information and belief at the date of its publication. The information given is designed only as a
guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a
warranty or quality specification. The information relates only to the specific material designated and may not be valid for
such material used in combination with any other material or in any process, unless specified in the text.

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