NAMA : MOCHAMAD RIFLI AL RAHMAN

NIM : 24030118130092

TUGAS : KIMIA ANORGANIK IV

Buatlah senyawa kompleks dengan atom pusat dan ligan yang memiliki 18 elektron berdasarkan
Donor Paid Method dan Neutral Ligand Method !

1. [H2Fe(CO)4]
- Menurut Neutral Ligand Method/Covalent Method :
· Fe = [Ar] 4s2 3d6 = 8 e-
· CO = 4 x 2 e- = 8 e-
· H = 2 x 1 e- = 2 e- +
= 18 e-
- Menurut Donor Paid Method/Ionic Method :
· Fe(II) = [Ar] 4s0 3d6 = 6 e-
· CO = 4 x 2 e- = 8 e-
· H- = 2 x 2 e- = 4 e- +
= 18 e-
2. Pd(PPh3)4
- Menurut Neutral Ligand Method/Covalent Method :
· Pd = [Kr] 4d10 = 10 e-
· PPh3 = 4 x 2 e- = 8 e- +
= 18 e-
- Menurut Donor Paid Method/Ionic Method :
· Pd(II) = [Kr] 4d10 = 10 e-
· PPh3 = 4 x 2 e- = 8 e- +
= 18 e-
3. (η5-C5H5)Fe(CO)2Cl
- Menurut Neutral Ligand Method/Covalent Method :
· Fe = [Ar] 4s2 3d6 = 8 e-
· (η5-C5H5) = 1 x 5 e- = 5 e-
· CO = 2 x 2 e- = 4 e-
· Cl = 1 x 1 e- = 1 e- +
= 18 e-
- Menurut Donor Paid Method/Ionic Method :
· Fe(II) = [Ar] 4s0 3d6 = 6 e-
· (η5-C5H5-) = 1 x 6 e- = 6 e-
· CO = 2 x 2 e- = 4 e-
· Cl- = 1 x 2 e- = 2 e- +
= 18 e-
4. [RhCl2(bpy)2]+
- Menurut Neutral Ligand Method/Covalent Method :
· Rh = [Kr] 4s1 3d8 = 9 e-
· Cl = 2 x 1 e- = 2 e-
· bpy = 2 x 4 e- = 8 e-
· Muatan = +1 = -1 e- +
= 18 e-
- Menurut Donor Paid Method/Ionic Method :
· Rh(III) = [Kr] 4s0 3d6 = 6 e-
· Cl- = 2 x 2 e- = 4 e-
· bpy = 2 x 4 e- = 8 e- +
= 18 e-
5. [W(CO)6]
- Menurut Neutral Ligand Method/Covalent Method :
· W = [Xe] 3f14 5d4 6s2 = 6 e-
· CO = 6 x 2 e- = 12 e- +
= 18 e-
- Menurut Donor Paid Method/Ionic Method :
· W(0) = [Xe] 3f14 5d4 6s2 = 6 e-
· CO = 6 x 2 e- = 12 e- +
= 18 e-
6. [Fe2(CO)9]
- Menurut Neutral Ligand Method/Covalent Method :
· Fe = [Ar] 4s2 3d6 = 8 e-
· CO = 3 x 2 e- = 6 e-
· μ−CO = 3 x 1 e- = 3 e-
· Fe – Fe = 1 e- = 1 e- +
= 18 e-
- Menurut Donor Paid Method/Ionic Method :
· Fe(0) = [Ar] 4s2 3d6 = 8 e-
· CO = 3 x 2 e- = 6 e-
· μ−CO = 3 x 1 e- = 3 e-
· Fe – Fe = 1 e- = 1 e- +
= 18 e-
7. [Ti(η5-C5H5)H]2(C2H2-C5H5)
- Menurut Neutral Ligand Method/Covalent Method :
· Ti = [Ar] 4s2 3d2 = 4 e-
· μ−H = 2 x 1 e- = 2 e-
· H = 1 x 1 e- = 1 e-
· (η5-C5H5) = 2 x 5 e- = 10 e-
· Ti−Ti = 1 x 1 e- = 1 e- +
 = 18 e-
- Menurut Donor Paid Method/Ionic Method :
· Ti(III) = [Ar] 4s0 3d1 = 1 e-
· μ−H = 2 x 1 e- = 2 e-
· H- = 1 x 2 e- = 2 e-
· (η5-C5H5-) = 2 x 6 e- = 12 e-
· Ti−Ti = 1 x 1 e- = 1 e- +
= 18 e-
8. Cp*ReO3
- Menurut Neutral Ligand Method/Covalent Method :
· Re = [Xe] 6s2 5d5 = 7 e-
· C5H5 = 1 x 5 e- = 5 e-
· O = 3 x 2 e- = 6 e- +
= 18 e-
- Menurut Donor Paid Method/Ionic Method :
· Re = [Xe] 6s0 5d3 = 4 e-
· C5H5- = 1 x 6 e- = 6 e-
· O2- = 2 x 4 e- = 8 e- +
= 18 e-
9. [Co(NH3)6]3+
- Menurut Neutral Ligand Method/Covalent Method :
· Co = [Ar] 4s2 3d7 = 9 e-
· NH3 = 6 x 2 e- = 12 e-
· Muatan = +3 = -3e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Co(III) = [Ar] 4s0 3d6 = 6 e-
· NH3 = 6 x 2 e- = 12 e-
= 18 e-
10. Fe(C5H5)2
- Menurut Neutral Ligand Method/Covalent Method :
· Fe = [Ar] 4s2 3d6 = 8 e-
· C5H5 = 2 x 5 e- = 10 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Fe(II) = [Ar] 4s0 3d6 = 6 e-
· C5H5- = 2 x 6 e- = 12 e- +
= 18 e-
11. CpMo(PMe3)2(C≡CMe)(CO)
- Menurut Neutral Ligand Method/Covalent Method :
· Mo = [Kr] 5s2 4d5 = 7 e-
· C5H5 = 1 x 5 e- = 5 e-
· PMe3 = 2 x 2 e- = 4 e-
· CO = 1 x 2 e- = 2 e-
· C≡CMe = 1 x 1 e- = 1 e-
· Muatan = +1 = -1e-
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Mo(III) = [Kr] 5s0 4d4 = 4 e-
· C5H5- = 1 x 6 e- = 6 e-
· PMe3 = 2 x 2 e- = 4 e-
· CO = 1 x 2 e- = 2 e-
· C≡CMe - = 1 x 2 e- = 2 e- +
= 18 e-
12. Ni(CO)4
- Menurut Neutral Ligand Method/Covalent Method :
· Ni = [Ar] 4s2 3d8 = 10 e-
· CO = 4 x 2 e- = 8 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Ni(0) = [Ar] 4s2 3d8 = 10 e-
· CO = 4 x 2 e- = 8 e- +
= 18 e-
13. Cr(η6-C6H6)(CO)3
- Menurut Neutral Ligand Method/Covalent Method :
· Cr = [Ar] 4s1 3d5 = 6 e-
· η6-C6H6 = 1 x 6 e- = 6 e-
· CO = 3 x 2 e- = 6 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Cr = [Ar] 4s1 3d5 = 6 e-
· η6-C6H6 = 1 x 6 e- = 6 e-
· CO = 3 x 2 e- = 6 e- +
= 18 e-
CpRu(CO)2{P(OR)3}]+
- Menurut Neutral Ligand Method/Covalent Method :
· Ru = [Kr] 5s1 4d7 = 8 e-
· Cp = 1 x 5 e- = 5 e-
 · CO = 2 x 2 e- = 4 e-
· P(OR)3 = 1 x 2 e- = 2 e-
· Muatan = +1 = -1 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Ru(II) = [Kr] 5s0 4d6 = 6 e-
· Cp- = 6 e- = 6 e-
· CO = 2 x 2 e- = 4 e-
· P(OR)3 = 1 x 2 e- = 2 e- +
= 18 e-
15. [trans-HOs(=CR)Cl(N=CCH3)(PR3)2]+
- Menurut Neutral Ligand Method/Covalent Method :
· Os = [Xe] 5d6 6s2 = 8 e-
· CR = 1 x 3 e- = 3 e-
· H = 1 x 1 e- = 1 e-
· Cl = 1 x 1 e- = 1 e-
· NCCH3 = 1 x 2 e- = 2 e-
· PR3 = 2 x 2 e- = 4 e-
· Muatan = -1 = -1 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Os (VI) = [Xe] 6s0 5d2 = 2 e-
· CR3- = 1 x 6 e- = 6 e-
· H- = 1 x 2 e- = 2 e-
· Cl- = 1 x 2 e- = 2 e-
· NCCH3 = 1 x 2 e- = 2 e-
· PR3 = 2 x 2 e- = 4 e- +
= 18 e-
16. [Cp2Ru2(μ-Br)(CO)4]+
- Menurut Neutral Ligand Method/Covalent Method :
· Ru = [Kr] 5s1 4d7 = 8 e-
· Cp = 1 x 5 e- = 6 e-
· μ-Br = 1 x 1 e- = 1 e-
· CO = 2 x 2 e- = 4 e-
· Muatan = +1 = -1 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Ru(II) = [Kr] 5s0 4d6 = 6 e-
· Cp- = 1 x 6 e- = 6 e-
· μ-Br- = 1 x 2 e- = 2 e-
· CO = 2 x 2 e- = 4 e- +
 = 18 e-
17. Ir4(CO)12
- Menurut Neutral Ligand Method/Covalent Method :
· Ir = [Xe] 6s2 5d7 = 9 e-
· CO = 3 x 2 e- = 6 e-
· Ir-Ir = 3 x 1 e- = 3 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Ir(0) = = [Xe] 6s2 5d7 = 9 e-
· CO = 3 x 2 e- = 6 e-
· Ir-Ir = 3 x 1 e- = 3 e- +
= 18 e-

18. [Fe2(μ-MeC=CMe)( μ-PR2)(CO)6]+

- Menurut Neutral Ligand Method/Covalent Method :
· Fe = [Ar] 4s2 3d6 = 8 e-
· μ-Me-C=C-Me = 1 x 2 e- = 2 e-
· μ-PR2 = 1 x 2 e- = 2 e-
-
· CO =3x2e = 6 e-
· Fe-Fe = 1 x 1 e- = 1 e-
· Muatan = +1 = -1 e- +
= 18 e-
- Menurut Neutral Ligand Method/Covalent Method :
· Fe = [Ar] 4s1 3d6 = 7 e-
· μ-Me-C=C-Me = 1 x 2 e- = 2 e-
· μ-PR2- = 1 x 2 e- = 2 e-
· CO = 3 x 2 e- = 6 e-
· Fe-Fe = 1 x 1 e- = 1 e- +
= 18 e-