Abstract
Cluster analysis (CA), discriminant analysis (DA) and principal component analysis (PCA) were comprehensively coupled to explore and identify the spatial and temporal variation and potential pollution sources in coastal water quality along Macau peninsula. The results show that the 12 months could be grouped into two periods, June–September and the remaining months, and the entire area divided into two clusters, one located at the western sides, and the other on the southeast and southern sides of the Macau peninsula. Through backward stepwise DA, pH, Cl−, TSS, Color and TP, Chloride, Color, NH4 +, DO, COD were discriminant variables of spatial and temporal variation, with 84.82 and 76.54% correct assignments, respectively. Fecal pollution, organic pollution and soil weathering are among the major sources for coastal water quality deterioration along Macau peninsula. This study illustrates that application of multivariate statistical techniques was beneficial to gain knowledge for further optimizing the monitoring network and controlling coastal water quality along Macau peninsula.





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References
American Public Health Association, American Water Works Association, Water Environment Federation (1992) Standard methods for the examination of water and wastewater. American Public Health Association, Washington, DC
Bowen RE, Depledge MH (2006) Rapid assessment of marine pollution (RAMP). Mar Pollut Bull 53:638–646
Goonetillekea A, Thomasb E, Ginnc S, Gilbert D (2005) Understanding the role of land use in urban stormwater quality management. J Environ Manag 74:31–42
Hamers T, van den Brink PJ, Mos L, van der Linden SC, Legler J, Koeman JH, Murk AJ (2003) Estrogenic and esterase-inhibiting potency in rainwater in relation to pesticide concentrations, sampling season and location. Environ Pollut 123:47–63
Helena B, Pardo R, Vega M, Barrado E, Fernandez JM, Fernandez L (2000) Temporal evolution of groundwater composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Water Res 34:807–816
Huang J, Du P, Ao C, Lei M, Zhao D, Wang Z (2007) Multivariate analysis for stormwater quality characteristics identification from different urban surface types in Macau. Bull Environ Contam Toxicol 79:650–654
Jiang H (2003) Environmental water chemistry. Chemical Industry Press, Beijing
Kuppusamy MR, Giridhar VV (2006) Factor analysis of water quality characteristics including trace metal speciation in the coastal environmental system of Chennai Ennore. Environ Int 32:174–179
Lattin J, Carroll D, Green P (2003) Analyzing multivariate data. Duxbury Press, New York
Otto M (1998) Multivariate methods. In: Kellner R, Mermet JM, Otto M, Widmer HM (eds) Analytical chemistry. Wiley-VCH, Weinheim, Germany, 916 pp
Ouyang Y, Nkedi-kizza P, Wu QT, Shinde D, Huang CH (2006) Assessment of seasonal variations in surface water quality. Water Res 60:3800–3810
Simeonov V, Stratis V, Samara JA, Zachariadis G, Voutsa D, Anthemidis A (2003) Assessment of the surface water quality in Northern Greece. Water Res 37:4119–4124
Singh KP, Mali A, Mohan D, Sinha S (2004) Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomti River (India)—a case study. Water Res 38:3980–3992
Singh KP, Malik A, Sinha S (2005) Water quality assessment and apportionment of pollution sources of Gomti River (India) using multivariate statistical techniques—a case study. Anal Chim Acta 538:355–374
The Statistics and Census Service (DSEC) (2007) Yearbook of statistics 2007. Government Printing Bureau, Macao. http://www.dsec.gov.mo
Vazquez A, Costoya M, Pena RM, Garcia S, Herrero C (2003) A rainwater quality monitoring network: a preliminary study of the composition of rainwater in Galicia (NW Spain). Chemosphere 51:375–386
Vega M, Pardo R, Barrado E, Deban L (1998) Assessment of seasonal and polluting effects on the quality of river water by exploratory data analysis. Water Res 32:3581–3592
Wunderlin DA, Diaz MDP, Ame MV, Pesce SF, Hued AC, Biston MLSA (2001) Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality. A case study: Suquia River Basin (Cordoba-Argentina). Water Res 35(12):2881–2894
Xi D, Sun Y, Liu X (1999) Environmental monitor. Higher Education Press, Beijing
Yamada K, Umehara T, Ichik A (1993) Study on statistical characteristics of nonpoint pollutants deposited in urban areas. Water Sci Technol 28:283–290
Zhou F, Guo H, Liu Y, Jiang Y (2007a) Chemometrics data analysis of marine water quality and source identification in Southern Hong Kong. Mar Pollut Bull 54:745–756
Zhou F, Huang GH, Guo H, Zhang W, Hao Z (2007b) Spatio-temporal patterns and source apportionment of coastal water pollution in eastern Hong Kong. Water Res 41:3429–3439
Zhou F, Liu Y, Guo H (2007c) Application of multivariate statistical methods to water quality assessment of the watercourses in Northwestern new territories, Hong Kong. Environ Monit Assess 132:1–13
Acknowledgements
This research was funded by the Department of Science and Technology of Fujian province as a Talented Youth scholar in Fujian Province (No. 2007F3093). The authors also sincerely thank to Mrs. Lee Mue-heong (Official Provisional Municipal Council of Macau) and Dr. Zhou Feng (Environmental School, Peking University) for the suggestions and help of data analysis.
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Huang, J., Ho, M. & Du, P. Assessment of temporal and spatial variation of coastal water quality and source identification along Macau peninsula. Stoch Environ Res Risk Assess 25, 353–361 (2011). https://doi.org/10.1007/s00477-010-0373-4
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DOI: https://doi.org/10.1007/s00477-010-0373-4